Ceric(IV) Ammonium Nitrate Mediated Phosphorylation of Alkenes: Easy Access to ( E )‐Vinylphosphonates | Zendy

Shen Jian | Zendy; Yu RuiXiao | Zendy; Luo Yan | Zendy; Zhu LiXuan | Zendy; Zhang Yue | Zendy; Wang Xue | Zendy; Xiao Bo | Zendy; Cheng JianBo | Zendy; Yang Bin | Zendy; Li GuiZhi | Zendy

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Ceric(IV) Ammonium Nitrate Mediated Phosphorylation of Alkenes: Easy Access to ( E )‐Vinylphosphonates

Author(s) -

Shen Jian,

Yu RuiXiao,

Luo Yan,

Zhu LiXuan,

Zhang Yue,

Wang Xue,

Xiao Bo,

Cheng JianBo,

Yang Bin,

Li GuiZhi

Publication year - 2019

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201900144

Subject(s) - ceric ammonium nitrate , chemistry , nitrate , ammonium , phosphorylation , organic chemistry , combinatorial chemistry , inorganic chemistry , biochemistry , polymer , grafting

An inexpensive Ceric(IV) ammonium nitrate mediated phosphorylation of alkenes has been developed. Without adding expensive metals and other additives, various ( E )‐alkenylphosphane oxides are obtained through an easy route in a one‐pot manner. Preliminary mechanistic studies reveal that a spontaneous elimination process is involved in this process.

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