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Ceric(IV) Ammonium Nitrate Mediated Phosphorylation of Alkenes: Easy Access to ( E )‐Vinylphosphonates
Author(s) -
Shen Jian,
Yu RuiXiao,
Luo Yan,
Zhu LiXuan,
Zhang Yue,
Wang Xue,
Xiao Bo,
Cheng JianBo,
Yang Bin,
Li GuiZhi
Publication year - 2019
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201900144
Subject(s) - ceric ammonium nitrate , chemistry , nitrate , ammonium , phosphorylation , organic chemistry , combinatorial chemistry , inorganic chemistry , biochemistry , polymer , grafting
An inexpensive Ceric(IV) ammonium nitrate mediated phosphorylation of alkenes has been developed. Without adding expensive metals and other additives, various ( E )‐alkenylphosphane oxides are obtained through an easy route in a one‐pot manner. Preliminary mechanistic studies reveal that a spontaneous elimination process is involved in this process.