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Regioselective Acetoxylation of Terminal Olefins Using a Palladium(II)–Thiadiazole Catalyst
Author(s) -
Li Xiaohan,
Sun Bin,
Zhou Jiadi,
Jin Can,
Yu Chuangming
Publication year - 2019
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201900128
Subject(s) - allylic rearrangement , chemistry , regioselectivity , palladium , catalysis , yield (engineering) , organic chemistry , medicinal chemistry , combinatorial chemistry , materials science , metallurgy
First‐time use of a palladium(II)–thiadiazole catalyst in the allylic oxidation of terminal olefins to linear allylic acetates. Employing this strategy, a range of allylic esters (20 examples) were synthesized in 43 % to 80 % yield with excellent regio‐ and stereoselectivities.
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