Valorization of Methyl Azelaaldehydate – A Vegetable Oil Based Platform Molecule for the Synthesis of Monomers through Stetter Reaction | Zendy

Charvieux Aubin | Zendy; Duc Vu Nam | Zendy; Duguet Nicolas | Zendy; Lemaire Marc | Zendy

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Valorization of Methyl Azelaaldehydate – A Vegetable Oil Based Platform Molecule for the Synthesis of Monomers through Stetter Reaction

Author(s) -

Charvieux Aubin,

Duc Vu Nam,

Duguet Nicolas,

Lemaire Marc

Publication year - 2019

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201801611

Subject(s) - monomer , adduct , chemistry , limiting , benzoin , organic chemistry , michael reaction , selectivity , molecule , catalysis , polymer , mechanical engineering , engineering

The valorization of vegetable oil‐derived methyl azelaaldehydate (methyl 9‐oxo‐nonanoate) to monomers was studied through NHC‐catalysed Stetter reaction. Among the Michael acceptors tested, dimethyl fumarate gave the highest selectivity (97 %) for the corresponding Stetter adduct, thus limiting the competing benzoin condensation.

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