Ruthenium‐Catalyzed Regioselective Direct  Ortho ‐Acyloxylation of Azoarenes with Carboxylic Acids via C–H Bond Activation | Zendy

Kianmehr Ebrahim | Zendy; Nasab Sepideh Bahrami | Zendy

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Ruthenium‐Catalyzed Regioselective Direct Ortho ‐Acyloxylation of Azoarenes with Carboxylic Acids via C–H Bond Activation

Author(s) -

Kianmehr Ebrahim,

Nasab Sepideh Bahrami

Publication year - 2019

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201801545

Subject(s) - chemistry , regioselectivity , ruthenium , catalysis , substrate (aquarium) , functional group , alkyl , aryl , organic chemistry , combinatorial chemistry , oceanography , polymer , geology

A Ru II ‐catalyzed highly regioselective C–H acyloxylation of azoarenes with inexpensive alkyl and aryl carboxylic acids as an acyloxylation agent is described. The reaction demonstrates a broad substrate scope and good functional group tolerance. This method provides a facile procedure to synthesize ortho ‐acyloxylated azoarene derivatives.

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