Synthesis of Heterohelicenes by a Catalytic Multi‐Component Povarov Reaction | Zendy

Viglianisi Caterina | Zendy; Biagioli Chiara | Zendy; Lippi Martina | Zendy; Pedicini Maria | Zendy; Villani Claudio | Zendy; Franzini Roberta | Zendy; Menichetti Stefano | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Synthesis of Heterohelicenes by a Catalytic Multi‐Component Povarov Reaction

Author(s) -

Viglianisi Caterina,

Biagioli Chiara,

Lippi Martina,

Pedicini Maria,

Villani Claudio,

Franzini Roberta,

Menichetti Stefano

Publication year - 2019

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201801489

Subject(s) - chemistry , adduct , catalysis , component (thermodynamics) , primary (astronomy) , organic chemistry , resolution (logic) , reaction conditions , combinatorial chemistry , polymer chemistry , physics , thermodynamics , astronomy , artificial intelligence , computer science

A multi‐component Povarov reaction was used for the preparation of [4], [5] and [6]aza‐ and azaoxahetero helical‐shaped compounds. The oxidation of the tetrahydroquinolinic primary Povarov adducts to the aromatic quinolines is mandatory to achieve a helical‐shaped structure and can be carried out in a one‐pot fashion with DDQ. Resolution of [5] and [6]heterohelicenes was successfully performed by chiral HPLC.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research