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Mechanistic Insights into FLP‐Catalyzed Iodoperfluoroalkylations
Author(s) -
Spittler Michael,
Helmecke Lucas,
Czekelius Constantin
Publication year - 2019
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201800866
Subject(s) - chemistry , catalysis , frustrated lewis pair , iodide , substrate (aquarium) , combinatorial chemistry , stereochemistry , lewis acids and bases , organic chemistry , oceanography , geology
The frustrated Lewis pair‐catalyzed iodoperfluoroalkylation of olefins, its substrate activation mode, and catalyst degradation pathways are mechanistically investigated by kinetic measurements. The transformation most likely proceeds via coordination of the phosphane to the perfluoroalkyl iodide and involves radical intermediates.