Synthesis and Properties of Acridine and Acridinium Dye Functionalized Bis(terpyridine) Ruthenium(II) Complexes | Zendy

Eberhard Jens | Zendy; Peuntinger Katrin | Zendy; Fröhlich Roland | Zendy; Guldi Dirk M. | Zendy; Mattay Jochen | Zendy

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Synthesis and Properties of Acridine and Acridinium Dye Functionalized Bis(terpyridine) Ruthenium(II) Complexes

Author(s) -

Eberhard Jens,

Peuntinger Katrin,

Fröhlich Roland,

Guldi Dirk M.,

Mattay Jochen

Publication year - 2018

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201800257

Subject(s) - terpyridine , ruthenium , chemistry , acridine , chromophore , linker , photochemistry , cyclic voltammetry , combinatorial chemistry , metal , electrochemistry , organic chemistry , catalysis , electrode , computer science , operating system

We present first principle studies on the rational design of an acridine/ N ‐methylacridinium dye (Acr/MeAcr + ) substituted terpyridine ligand to investigate if these chromophores can act as triplet‐energy storage units in bis(terpyridine) ruthenium(II) complexes. We studied the influence of the dye form (Acr/MeAcr + ) as well as the interconnecting linker unit (none, 4‐phenyl, or 5‐thien‐2‐yl) and investigated these aspects by steady‐state/time‐resolved spectroscopy, cyclic voltammetry, X‐ray structure analysis, and DFT calculations.

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