Cobalt(II)‐Catalyzed  N ‐Acylation of Amines through a Transamidation Reaction | Zendy

Ma Juan | Zendy; Zhang Feng | Zendy; Zhang Jingyu | Zendy; Gong Hang | Zendy

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Cobalt(II)‐Catalyzed N ‐Acylation of Amines through a Transamidation Reaction

Author(s) -

Ma Juan,

Zhang Feng,

Zhang Jingyu,

Gong Hang

Publication year - 2018

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201800253

Subject(s) - chemistry , catalysis , acylation , cobalt , primary (astronomy) , dimethylformamide , organic chemistry , combinatorial chemistry , reaction conditions , medicinal chemistry , solvent , physics , astronomy

A practical protocol has been developed for a Co(OAc) 2 · 4H 2 O‐catalyzed transamidation reaction. The reaction gives high yields and uses N , N ‐dimethylformamide and other amides as carbonyl sources. The protocol is rapid and simple, and it does not require any acids, bases, ligands, or other additives. It works well for a wide range of primary, secondary, and heterocyclic amines.

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