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Construction of the Oxazolidinone Framework from Propargylamine and CO 2 in Air at Ambient Temperature: Catalytic Effect of a Gold Complex Featuring an L 2 /Z‐Type Ligand
Author(s) -
Inagaki Fuyuhiko,
Maeda Kakeru,
Nakazawa Kenta,
Mukai Chisato
Publication year - 2018
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201800228
Subject(s) - chemistry , catalysis , carboxylation , ligand (biochemistry) , borane , medicinal chemistry , metal , stereochemistry , combinatorial chemistry , inorganic chemistry , organic chemistry , receptor , biochemistry
The metal‐catalyzed carboxylation of propargylamines with aerial CO 2 at room temperature to form 5‐methyleneoxazolidin‐2‐one derivatives has been developed. In this reaction, the catalyst [Au(dpb F )]X featuring a Z‐type ligand gave the best results, presumably due to the σ‐acceptance of the borane atom.