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Fluorine‐Containing Functionalized Cyclopentene Scaffolds Through Ring Contraction and Deoxofluorination of Various Substituted Cyclohexenes
Author(s) -
Remete Attila Márió,
n Melinda,
Fustero Santos,
Haukka Matti,
Fülöp Ferenc,
Kiss Loránd
Publication year - 2018
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201800057
Subject(s) - cyclopentene , alicyclic compound , chemistry , fluorine , ring (chemistry) , polymer chemistry , contraction (grammar) , difluoride , organic chemistry , catalysis , medicine
The fluorination of some highly‐functionalized cyclopentene derivatives, obtained from various substituted cyclohexenes through a ring‐opening/ring‐contraction procedure, has been investigated. The transformations were found to be highly substrate dependent, and led to the formation of various functionalized alicyclic compounds or heterocycles containing allyl difluoride or vinyl fluoride moieties.