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Synthesis of Secondary Amides through the Palladium(II)‐Catalyzed Aminocarbonylation of Arylboronic Acids with Amines or Hydrazines and Carbon Monoxide
Author(s) -
Zhang Jin,
Ma Yuqiang,
Ma Yangmin
Publication year - 2018
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201701802
Subject(s) - chemistry , palladium , carbon monoxide , catalysis , organic chemistry , carbonylation , combinatorial chemistry
A new Pd‐catalyzed aminocarbonylation of arylboronic acids with amines or phenylhydrazines has been developed. Various secondary amides were produced from readily available substrates and cheap common metal catalysts in a CO atmosphere (balloon). Remarkably, we presents the first example of aminocarbonylations between arylboronic acids and phenylhydrazines.