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Synthesis of Fused B‐Containing Heterocyclic Compounds and Their Relevant Optical Properties
Author(s) -
An Zhenyu,
Wu Mingzhong,
Kang Jie,
Ni Jixiang,
Qi Zhenjie,
Yuan Bingxiang,
Yan Rulong
Publication year - 2018
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201701790
Subject(s) - chemistry , spectroscopy , potassium , ultraviolet visible spectroscopy , combinatorial chemistry , computational chemistry , organic chemistry , quantum mechanics , physics
A series of fused 4,5‐borazaropyrrolo[1,2‐ a ]quinolines have been prepared from potassium organotrifluoroborates and substituted 1‐(2‐aminophenyl)pyrroles via direct formation of C–B and N–B bonds. The target products were obtained in moderate to high yields under mild conditions. The optical properties of some products were investigated by UV/Vis spectroscopy and spectrofluorometry. Moreover, the influence of structural modification on the spectroscopic and electronic properties was studied by DFT calculations.