Synthesis of α‐Fluorinated Acrylates by a Palladium‐Catalyzed Decarboxylative Olefination Reaction | Zendy

Bouazzaoui Ouafa | Zendy; Rousée Kevin | Zendy; Mulengi Joseph Kajima | Zendy; Pannecoucke Xavier | Zendy; Bouillon JeanPhilippe | Zendy; CouveBonnaire Samuel | Zendy

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Synthesis of α‐Fluorinated Acrylates by a Palladium‐Catalyzed Decarboxylative Olefination Reaction

Author(s) -

Bouazzaoui Ouafa,

Rousée Kevin,

Mulengi Joseph Kajima,

Pannecoucke Xavier,

Bouillon JeanPhilippe,

CouveBonnaire Samuel

Publication year - 2018

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201701709

Subject(s) - chemistry , decarboxylation , palladium , catalysis , organic chemistry , ligand (biochemistry) , combinatorial chemistry , biochemistry , receptor

Ligand‐free palladium‐catalyzed subsequent decarboxylation/olefination reaction between 2‐fluorinated acrylates and benzoic acids is reported. Valuable trisubstituted 2‐fluoroacrylates and 2‐trifluoromethylacrylates were produced in low to excellent yields, which constitutes a new interesting greener synthetic alternative to these fluorinated molecules.

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