Synthesis, Characterization, and Properties of Energetic Compounds Based on a CH 2 ‐Bridged Dinitromethyl Explosophore | Zendy

Huang Haifeng | Zendy; Shi Yameng | Zendy; Yu Yao | Zendy; Yang Jun | Zendy

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Synthesis, Characterization, and Properties of Energetic Compounds Based on a CH 2 ‐Bridged Dinitromethyl Explosophore

Author(s) -

Huang Haifeng,

Shi Yameng,

Yu Yao,

Yang Jun

Publication year - 2018

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201701528

Subject(s) - chemistry , detonation , thermal stability , energetic material , standard enthalpy of formation , elemental analysis , single crystal , crystallography , infrared spectroscopy , characterization (materials science) , nuclear magnetic resonance spectroscopy , spectroscopy , diffraction , crystal structure , x ray crystallography , stereochemistry , organic chemistry , nanotechnology , explosive material , physics , quantum mechanics , optics , materials science

A series of energetic salts based on the 1,1,3,3‐tetranitropropane‐1,3‐diide (TNP) dianion have been prepared and fully characterized by NMR and IR spectroscopy, elemental analysis, and single‐crystal X‐ray diffraction. Their thermal stability ( T d = 111.0–180.9 °C) and sensitivities to mechanical stimuli (IS = 2–5 J; FS = 80–128 N) have been measured. Additionally, their heats of formation (–369.8 to 347.1 kJ mol –1 ) and detonation performances ( P = 25.0–37.0 GPa; v D = 7675–9104 m s –1 ) have been calculated.

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