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Iron‐Nitrate‐Catalyzed Oxidative Esterification of Aldehydes and Alcohols with N ‐Hydroxyphthalimide: Efficient Synthesis of N ‐Hydroxyimide Esters
Author(s) -
Xu Xiaohe,
Sun Jian,
Lin Yuyan,
Cheng Jingya,
Li Pingping,
Jiang Xiaoying,
Bai Renren,
Xie Yuanyuan
Publication year - 2017
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201701411
Subject(s) - chemistry , catalysis , substrate (aquarium) , oxidative phosphorylation , organic chemistry , nitrate , alcohol oxidation , scope (computer science) , alcohol , oxidative coupling of methane , combinatorial chemistry , biochemistry , oceanography , computer science , programming language , geology
An Fe(NO 3 ) 3 · 9H 2 O‐catalyzed cross‐dehydrogenative coupling reaction between N ‐hydroxyphthalimide (NHPI) or N ‐hydroxysuccinimide (NHSI) and aldehydes or alcohols in air is described. This transformation represents an efficient approach to the preparation of N ‐hydroxyimide ester derivatives in moderate to excellent yields, and has a wide substrate scope.