A Convenient Palladium‐Catalyzed Aminocarbonylation of Aryl Iodides to Primary Amides under Gas‐Free Conditions | Zendy

Qi Xinxin | Zendy; Ai HanJun | Zendy; Cai ChuangXu | Zendy; Peng JinBao | Zendy; Ying Jun | Zendy; Wu XiaoFeng | Zendy

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A Convenient Palladium‐Catalyzed Aminocarbonylation of Aryl Iodides to Primary Amides under Gas‐Free Conditions

Author(s) -

Qi Xinxin,

Ai HanJun,

Cai ChuangXu,

Peng JinBao,

Ying Jun,

Wu XiaoFeng

Publication year - 2017

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201701105

Subject(s) - chemistry , palladium , catalysis , aryl , primary (astronomy) , formic acid , organic chemistry , ammonium , ammonium carbonate , combinatorial chemistry , inorganic chemistry , alkyl , physics , astronomy

A convenient procedure for the synthesis of aromatic primary amides through palladium‐catalyzed aminocarbonylation of aryl iodides has been developed. With ammonium hydrogen carbonate as the solid nitrogen source and formic acid as the liquid CO source, a variety of primary amides were obtained in moderate to excellent yields under gas‐free conditions.

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