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A Convenient Palladium‐Catalyzed Aminocarbonylation of Aryl Iodides to Primary Amides under Gas‐Free Conditions
Author(s) -
Qi Xinxin,
Ai HanJun,
Cai ChuangXu,
Peng JinBao,
Ying Jun,
Wu XiaoFeng
Publication year - 2017
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201701105
Subject(s) - chemistry , palladium , catalysis , aryl , primary (astronomy) , formic acid , organic chemistry , ammonium , ammonium carbonate , combinatorial chemistry , inorganic chemistry , alkyl , physics , astronomy
A convenient procedure for the synthesis of aromatic primary amides through palladium‐catalyzed aminocarbonylation of aryl iodides has been developed. With ammonium hydrogen carbonate as the solid nitrogen source and formic acid as the liquid CO source, a variety of primary amides were obtained in moderate to excellent yields under gas‐free conditions.