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Diels–Alder and Formal Diels–Alder Cycloaddition Reactions of Ynamines and Ynamides
Author(s) -
Duret Guillaume,
Le Fouler Vincent,
Bisseret Philippe,
Bizet Vincent,
Blanchard Nicolas
Publication year - 2017
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201700986
Subject(s) - cycloaddition , chemistry , context (archaeology) , diels–alder reaction , organic chemistry , catalysis , archaeology , history
Nitrogen‐substituted alkynes such as ynamines and ynamides are competent partners in [4+2] cycloaddition reactions. This microreview aims to discuss in a historical context the main achievements in the work on this class of reactions that leads to valuable nitrogen‐containing heterocycles in a single‐step fashion. In the last section, our own work in the field of inverse‐electron‐demand Diels–Alder reactions between ynamides and pyrimidines is discussed.