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Direct Aerobic Oxidative Reactions of 2‐Hydroxyacetophenones
Author(s) -
Sahoo Subas Chandra,
Nath Utpal,
Pan Subhas Chandra
Publication year - 2017
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201700909
Subject(s) - chemistry , oxidative phosphorylation , redox , organic chemistry , combinatorial chemistry , biochemistry
Valuable and direct aerobic oxidation reactions of 2‐hydroxyacetophenones were explored. The concept was based on the in situ treatment of small quantities of aerobically formed α‐keto aldehydes that drove the reactions to the corresponding products. This new strategy was applied for a variety of oxidative reactions of 2‐hydroxyacetophenones, and valuable products such as phthalides, quinoxalines, and α‐keto amides were obtained in good to high yields.