Scalable Flow Synthesis of [6,6]‐Phenyl‐C 61 ‐butyric Acid Methyl Ester (PCBM) using a Flow Photoreactor with a Sodium Lamp | Zendy

Ueda Mitsuhiro | Zendy; Imai Naoyuki | Zendy; Yoshida Shunsuke | Zendy; Yasuda Hiroshi | Zendy; Fukuyama Takahide | Zendy; Ryu Ilhyong | Zendy

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Scalable Flow Synthesis of [6,6]‐Phenyl‐C 61 ‐butyric Acid Methyl Ester (PCBM) using a Flow Photoreactor with a Sodium Lamp

Author(s) -

Ueda Mitsuhiro,

Imai Naoyuki,

Yoshida Shunsuke,

Yasuda Hiroshi,

Fukuyama Takahide,

Ryu Ilhyong

Publication year - 2017

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201700745

Subject(s) - chemistry , photoisomerization , flow chemistry , butyric acid , sodium vapor lamp , organic chemistry , photochemistry , catalysis , isomerization , physics , optics

An efficient flow system was constructed for the synthesis of [6,6]‐phenyl‐C 61 ‐butyric acid methyl ester (PCBM); the process involved flow [2+1] addition of C 60 and subsequent flow photoisomerization of the resulting fulleroid to PCBM by using a flow photoreactor in combination with an Na lamp. With the present flow system, a scalable synthesis of PCBM (0.79 g/3.3 h) was achieved by continuous operation for 3.3 h.

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