Manganese(III) Acetate Mediated C–H Sulfonylation of 1,4‐Dimethoxybenzenes with Sodium and Lithium Sulfinates | Zendy

Liang Shuai | Zendy; Ren Yueling | Zendy; Manolikakes Georg | Zendy

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Manganese(III) Acetate Mediated C–H Sulfonylation of 1,4‐Dimethoxybenzenes with Sodium and Lithium Sulfinates

Author(s) -

Liang Shuai,

Ren Yueling,

Manolikakes Georg

Publication year - 2017

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201700713

Subject(s) - chemistry , manganese , reagent , lithium (medication) , sodium , oxidative coupling of methane , oxidative phosphorylation , sulfur dioxide , organic chemistry , sulfur , inorganic chemistry , catalysis , biochemistry , medicine , endocrinology

A simple and mild Mn(OAc) 3 ‐promoted oxidative coupling of 1,4‐dimethoxybenzenes with sodium and lithium sulfinates was developed. The reaction proceeded readily at room temperature in air, and various sulfones were synthesized in moderate to high yields. In addition, a straightforward approach for the conversion of organolithium reagents and sulfur dioxide into sulfonylated 1,4‐dimethoxybenzenes was explored.

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