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Trifluoromethylselenolation and Fluoroalkylselenolation of Alkenes by Electrophilic Addition
Author(s) -
Ghiazza Clément,
Glenadel Quentin,
Tlili Anis,
Billard Thierry
Publication year - 2017
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201700643
Subject(s) - electrophile , chemistry , electrophilic addition , combinatorial chemistry , organic chemistry , molecule , in situ , alkene , catalysis
Fluoroalkylselenylated compounds are still underused due to a lack of efficient synthetic methods. Herein, we describe an efficient synthesis of α‐chloro‐β‐fluoroalkylselenolated molecules through electrophilic addition of in situ preformed fluoroalkylselenyl chlorides onto alkenes. The obtained compounds constitute valuable building blocks for further applications.