Back Cover: Visible‐Light, Photoredox‐Mediated Oxidative Tandem Nitroso‐Diels–Alder Reaction of Arylhydroxylamines with Conjugated Dienes (Eur. J. Org. Chem. 15/2017) | Zendy

Santacroce Veronica | Zendy; Duboc Raphael | Zendy; Malacria Max | Zendy; Maestri Giovanni | Zendy; Masson Geraldine | Zendy

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Back Cover: Visible‐Light, Photoredox‐Mediated Oxidative Tandem Nitroso‐Diels–Alder Reaction of Arylhydroxylamines with Conjugated Dienes (Eur. J. Org. Chem. 15/2017)

Author(s) -

Santacroce Veronica,

Duboc Raphael,

Malacria Max,

Maestri Giovanni,

Masson Geraldine

Publication year - 2017

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201700480

Subject(s) - chemistry , nitroso , oxidizing agent , conjugated system , tandem , nitroso compounds , diels–alder reaction , photochemistry , functional group , oxidative phosphorylation , photocatalysis , combinatorial chemistry , organic chemistry , catalysis , materials science , composite material , polymer , biochemistry

The cover picture shows the nitroso‐Diels–Alder reaction between hydroxylamines and conjugated dienes. This tandem process is achieved by an in situ aerobic oxidation. In fact, the Ru 2+ photocatalyst can selectively oxidize hydroxylamines to nitroso intermediates, allowing the one‐pot synthesis of the desired 3,6‐dihydro‐1,2‐oxazines. These oxidizing conditions show a broad functional‐group tolerance towards both reaction partners, validating the synthetic potential of the method. Details are discussed in the Communication by G. Masson et al. on page 2095 ff (DOI: 10.1002/ejoc.201601492 ).

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