Diastereoselective Synthesis of  trans ‐2,3‐Diaryl(heteroaryl)‐3,6‐dihydropyrans by an Allylboration/Ring‐Closing‐Metathesis Sequence | Zendy

Nocquet PierreAntoine | Zendy; Corbu Andrei | Zendy; Meerpoel Lieven | Zendy; Stansfield Ian | Zendy; Berthelot Didier | Zendy; Angibaud Patrick | Zendy; Cossy Janine | Zendy

Premium

Diastereoselective Synthesis of trans ‐2,3‐Diaryl(heteroaryl)‐3,6‐dihydropyrans by an Allylboration/Ring‐Closing‐Metathesis Sequence

Author(s) -

Nocquet PierreAntoine,

Corbu Andrei,

Meerpoel Lieven,

Stansfield Ian,

Berthelot Didier,

Angibaud Patrick,

Cossy Janine

Publication year - 2017

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201700448

Subject(s) - chemistry , dihydropyran , ring closing metathesis , metathesis , allylic rearrangement , stereochemistry , sequence (biology) , ring (chemistry) , organic chemistry , catalysis , biochemistry , polymer , polymerization

trans ‐2,3‐Diaryl(heteroaryl)‐dihydropyrans were synthesized by an allylboration/ring‐closing‐metathesis sequence, using allylboranes formed in situ from the corresponding allylic alcohols. Aryl(heteroaryl) substituents were thus installed diastereoselectively onto dihydropyran rings in a trans fashion. These disubstituted dihydropyrans were further transformed into monosaccharide‐like tetrahydropyrans.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research