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Palladium‐Catalyzed Chemo‐ and Regioselective Oxidative Cross‐Dehydrogenative Coupling of Acetanilides with Benzothiazole
Author(s) -
Kianmehr Ebrahim,
Fardpour Maryam,
Kharat Ali Nemati
Publication year - 2017
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201700290
Subject(s) - acetanilide , benzothiazole , chemistry , regioselectivity , palladium , catalysis , oxidative phosphorylation , combinatorial chemistry , oxidative coupling of methane , coupling (piping) , organic chemistry , metallurgy , biochemistry , materials science
A practical, versatile, and efficient method for the palladium‐catalyzed direct heteroarylation of acetanilides was developed. In this method, a wide range of acetanilides bearing electron‐donating and electron‐withdrawing groups are well tolerated, and the desired 2‐arylbenzothiazoles are generated in good to high yields through a cross‐dehydrogenative coupling process.

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