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Rh 2 (esp) 2 : An Efficient Catalyst for O–H Insertion Reactions of Carboxylic Acids into Acceptor/Acceptor Diazo Compounds (Eur. J. Org. Chem. 13/2016)
Author(s) -
Hunter Arianne C.,
Chinthapally Kiran,
Sharma Indrajeet
Publication year - 2016
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201690024
Subject(s) - diazo , chemistry , rhodium , carbenoid , catalysis , acceptor , decomposition , carboxylic acid , medicinal chemistry , photochemistry , organic chemistry , physics , condensed matter physics
The cover picture shows O–H insertion reactions of carboxylic acids into highly stabilized acceptor/acceptor diazo compounds. Rh 2 (esp) 2 acts as an effective catalyst for the decomposition of these stable diazo compounds to form a reactive rhodium carbenoid. The carboxylic acid comes into contact with the reactive rhodium carbenoid and undergoes an O–H insertion reaction to release the Rh catalyst. Rh 2 (esp) 2 now completes its catalytic cycle and is available for the decomposition of another diazo molecule. Details are discussed in the article by I. Sharma et al. on p. 2260 ff .