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Visible‐Light‐Mediated 5‐ exo ‐ dig Cyclizations of Amidyl Radicals
Author(s) -
Reina Daniel Fernandez,
Dauncey Elizabeth M.,
Morcillo Sara P.,
Svejstrup Thomas D.,
Popescu Mihai V.,
Douglas James J.,
Sheikh Nadeem S.,
Leonori Daniele
Publication year - 2017
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201601607
Subject(s) - chemistry , hydroamination , radical , dig , pyrrolidinones , methylene , photochemistry , visible spectrum , organic chemistry , catalysis , physics , computer security , optoelectronics , computer science
A visible‐light‐mediated synthesis of 5‐methylene‐pyrrolidinones is reported. This constitutes to the first reported example of a 5‐ exo ‐ dig hydroamination reaction involving a nitrogen‐centered radical.
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