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Addition of Mixed (Alkenyl)dialkylzincates to Vicinal Diketo Esters
Author(s) -
Selter Lars,
Harms Klaus,
Koert Ulrich
Publication year - 2017
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201601598
Subject(s) - chemistry , alkylation , vicinal , regioselectivity , reagent , organic chemistry , combinatorial chemistry , catalysis
Methods for the regioselective alkylation, arylation, and alkenylation of α,β‐diketo esters using organozinc reagents are reported. Alkylation and arylation at the α‐position is possible using diorganozinc compounds. Alkenylation can be achieved using mixed (alkenyl)dineopentylzincates.