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Insights into the Scholl Coupling Reaction: A Key Transformation of Relevance to the Synthesis of Graphenes and Related Systems
Author(s) -
Little Mark S.,
Yeates Stephen G.,
Alwattar Aula A.,
Heard Kane W. J.,
Raftery James,
Edwards Alyn C.,
Parry Adam. V. S.,
Quayle Peter
Publication year - 2017
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201601580
Subject(s) - chemistry , chrysene , coupling reaction , coupling (piping) , relevance (law) , organic chemistry , catalysis , mechanical engineering , pyrene , political science , law , engineering
The Scholl‐type reactions of 4,10‐disubstituted chrysene derivatives proceeded by variegated and unexpected oxidation/coupling pathways. These observations serve as a cautionary note when attempting to employ the Scholl reaction in target‐oriented materials synthesis.