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Photoredox/Nickel Dual Catalysis for the C(sp 3 )–C(sp 3 ) Cross‐Coupling of Alkylsilicates with Alkyl Halides
Author(s) -
Lévêque Christophe,
Corcé Vincent,
Chenneberg Ludwig,
Ollivier Cyril,
Fensterbank Louis
Publication year - 2017
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201601571
Subject(s) - halide , chemistry , alkyl , nickel , catalysis , coupling reaction , carbon fibers , medicinal chemistry , photochemistry , organic chemistry , materials science , composite number , composite material
Alkylsilicates were engaged under photoredox/nickel dual catalysis conditions with alkyl halides for the first time. The C(sp 3 )–C(sp 3 ) cross‐coupling products were obtained in moderate yields and were accompanied by the homocoupling products of the alkyl halide derivatives. These promising findings are strongly suggestive of the high synthetic potential of the dual catalytic approach for the forging of alkyl carbon–carbon bonds.