[( para ‐Cymene)Ru(dppp)Cl][PF 6 ]‐Catalysed Stereospecific Synthesis of  O ‐Dienyl Esters, and Evaluation of the Anticancer Activity of a Long‐Chain Fatty Acid  O ‐Dienyl Ester | Zendy

Jena Rajesh K. | Zendy; Rajesh Y. | Zendy; Mandal Mahitosh | Zendy; Bhattacharjee Manish | Zendy

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[( para ‐Cymene)Ru(dppp)Cl][PF 6 ]‐Catalysed Stereospecific Synthesis of O ‐Dienyl Esters, and Evaluation of the Anticancer Activity of a Long‐Chain Fatty Acid O ‐Dienyl Ester

Author(s) -

Jena Rajesh K.,

Rajesh Y.,

Mandal Mahitosh,

Bhattacharjee Manish

Publication year - 2017

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201601557

Subject(s) - chemistry , stereospecificity , dehydration , p cymene , medicinal chemistry , double bond , organic chemistry , stereochemistry , ruthenium , catalysis , biochemistry

O ‐Dienyl esters are obtained through the regio‐ and stereospecific addition of both aromatic and aliphatic carboxylic acids to terminal propargylic alcohols, with the sequential formation of a carbon–oxygen bond and dehydration, in the presence of [( p ‐cymene)Ru(dppp)Cl][PF 6 ] ( 1 ). Also, the cytotoxicity and anticancer activity of the newly synthesized O ‐dienyl ester ( Z )‐3‐methylbuta‐1,3‐dienyl oleate have been investigated.

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