Conversion of Cyclohexanones to Alkyl Aryl Ethers by Using a Pd/C–Ethylene System | Zendy

ElDeeb Ibrahim Yussif | Zendy; Tian Miaomiao | Zendy; Funakoshi Tatsuya | Zendy; Matsubara Ryosuke | Zendy; Hayashi Masahiko | Zendy

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Conversion of Cyclohexanones to Alkyl Aryl Ethers by Using a Pd/C–Ethylene System

Author(s) -

ElDeeb Ibrahim Yussif,

Tian Miaomiao,

Funakoshi Tatsuya,

Matsubara Ryosuke,

Hayashi Masahiko

Publication year - 2017

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201601362

Subject(s) - chemistry , ethylene , cyclohexanone , alkyl , aryl , catalysis , cyclohexenone , ether , organic chemistry , phenols , phenol , hydrogen , polymer chemistry

The conversion of cyclohexanone and substituted cyclohexanones into alkyl aryl ethers by using a Pd/C–ethylene system is discussed, with ethylene functioning as a hydrogen acceptor. The ether products are easily transformed into the corresponding phenols by treatment with BBr 3 . The direct conversion of cyclohexenone into phenol in the presence of a catalytic amount of Pd/C under an ethylene atmosphere is also described.

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