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Ruthenium‐Catalyzed Addition of Carboxylic Acids to Propargylic Alcohols: An Easy Route to O ‐Dienyl Esters and Their Tandem Atom‐Transfer Radical Polymerization
Author(s) -
Jena Rajesh K.,
Das Uttam K.,
Ghorai Arijit,
Bhattacharjee Manish
Publication year - 2016
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201601091
Subject(s) - chemistry , ruthenium , catalysis , stereoselectivity , tandem , atom transfer radical polymerization , carboxylic acid , atom economy , carbon atom , organic chemistry , polymerization , medicinal chemistry , polymer chemistry , combinatorial chemistry , alkyl , materials science , polymer , composite material
A ruthenium‐catalyzed one‐pot synthesis of O ‐dienyl esters through the regio‐ and stereoselective addition of carboxylic acids to propargylic alcohols, and the atom‐transfer radical polymerisation of the products have been developed. The initial addition reaction takes place through the formation of a carbon–oxygen bond followed by dehydration.