A Brønsted Acid–Primary Amine as a Synergistic Catalyst for Stereoselective Asymmetric Diels–Alder Reactions | Zendy

Ramachary Dhevalapally B. | Zendy; Reddy P. Sreekanth | Zendy; Shruthi Kodambahalli S. | Zendy; Madhavachary R. | Zendy; Reddy P. V. Govardhana | Zendy

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A Brønsted Acid–Primary Amine as a Synergistic Catalyst for Stereoselective Asymmetric Diels–Alder Reactions

Author(s) -

Ramachary Dhevalapally B.,

Reddy P. Sreekanth,

Shruthi Kodambahalli S.,

Madhavachary R.,

Reddy P. V. Govardhana

Publication year - 2016

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201601011

Subject(s) - chemistry , stereoselectivity , brønsted–lowry acid–base theory , primary (astronomy) , amine gas treating , catalysis , organic chemistry , diels–alder reaction , acid catalysis , physics , astronomy

Herein, we present the Brønsted‐acid‐controlled, primary‐amine‐catalyzed stereoselective asymmetric synthesis of druglike six‐membered spirooxindoles from simple aliphatic substrates through a Barbas [4+2]‐cycloaddition reaction by using 2‐aminobuta‐1,3‐diene catalysis under ambient conditions.

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