Selective  gem ‐Dichlorination of Isonitriles Mediated by (Dichloroiodo)benzene | Zendy

Zhang Haifeng | Zendy; Shi Dongdong | Zendy; Ren Shaobo | Zendy; Jin Hongwei | Zendy; Liu Yunkui | Zendy

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Selective gem ‐Dichlorination of Isonitriles Mediated by (Dichloroiodo)benzene

Author(s) -

Zhang Haifeng,

Shi Dongdong,

Ren Shaobo,

Jin Hongwei,

Liu Yunkui

Publication year - 2016

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201600667

Subject(s) - chemistry , benzophenone , reagent , benzene , imine , combinatorial chemistry , organic chemistry , medicinal chemistry , benzene derivatives , chemical synthesis , catalysis , biochemistry , in vitro

A selective gem ‐dichlorination of isonitriles has been successfully achieved by using (dichloroiodo)benzene as a chlorinating reagent. The reaction gives N ‐arylcarbonimidic dichlorides in high yields under mild and metal‐free conditions. The application of N ‐arylcarbonimidic dichlorides as synthetic intermediates in the synthesis of 2,2,3,3‐tetrachloroaziridine 4 , propyl formimidate 5 , benzophenone imine 6 , and 6‐chlorophenanthridine ( 3a ) was also investigated.

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