Catalyst‐Free S–S Bond Insertion Reaction of a Donor/Acceptor‐Free Carbene by a Radical Process: A Combined Experimental and Computational Study | Zendy

Zheng Yang | Zendy; Bian Rongjian | Zendy; Zhang Xiaolu | Zendy; Yao Ruwei | Zendy; Qiu Lihua | Zendy; Bao Xiaoguang | Zendy; Xu Xinfang | Zendy

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Catalyst‐Free S–S Bond Insertion Reaction of a Donor/Acceptor‐Free Carbene by a Radical Process: A Combined Experimental and Computational Study

Author(s) -

Zheng Yang,

Bian Rongjian,

Zhang Xiaolu,

Yao Ruwei,

Qiu Lihua,

Bao Xiaoguang,

Xu Xinfang

Publication year - 2016

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201600664

Subject(s) - chemistry , carbene , catalysis , acceptor , photochemistry , free radical reaction , radical , organic chemistry , physics , condensed matter physics

Herein, a donor/acceptor‐free carbene insertion reaction of an S–S bond through a radical process is presented. This catalyst‐free reaction was thermally induced and provided the dithioketal products in moderate to high yields. A mechanism involving radical intermediates was proposed according to the computational study, and these intermediates were verified experimentally and intercepted for the first time by using a cross‐coupling reaction.

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