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Emergence of Copper‐Mediated Formation of C–C Bonds
Author(s) -
Maaliki Carine,
Thiery Emilie,
Thibonnet Jérôme
Publication year - 2017
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201600540
Subject(s) - chemistry , sonogashira coupling , coupling reaction , copper , domino , heteroatom , carbon fibers , coupling (piping) , combinatorial chemistry , catalysis , organic chemistry , photochemistry , palladium , ring (chemistry) , mechanical engineering , materials science , composite number , engineering , composite material
Copper‐catalyzed cross‐coupling reactions have found widespread application in carbon–carbon or carbon–heteroatom bond formation. The relatively low toxicity, ease of handling, and low cost of these versatile complexes make them attractive for the elaboration of new methodologies and for the obtaining of new compounds. We focus on recent methods for the copper‐mediated formation of carbon–carbon bonds illustrated by different coupling reactions: cross‐dehydrogenative coupling, decarboxylative cross‐coupling, Sonogashira‐type reactions, Suzuki‐type reactions, and Neigishi‐type reactions. Domino reactions and, finally, more atypical reactions are also illustrated.