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Nickel(0)‐Catalyzed N ‐Allylation of Amides and p ‐Toluenesulfonamide with Allylic Alcohols under Neat and Neutral Conditions
Author(s) -
Azizi Mohamed Salah,
Edder Youssef,
Karim Abdallah,
Sauthier Mathieu
Publication year - 2016
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201600500
Subject(s) - chemistry , allylic rearrangement , catalysis , nickel , medicinal chemistry , organic chemistry
Nickel(0)‐catalyzed direct N ‐allylation of amides and p ‐toluenesulfonamide with allylic alcohols took place in the presence of Ni 0 –diphosphine complexes. The corresponding N ‐allylated (and/or N , N ‐diallylated) products were obtained in moderate to high yields under neutral conditions.