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Cleavage of the Carbon–Carbon Triple Bonds of Arylacetylenes for the Synthesis of Arylnitriles without a Metal Catalyst
Author(s) -
Lin Yuanguang,
Song Qiuling
Publication year - 2016
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201600438
Subject(s) - chemistry , triple bond , alkyne , catalysis , reinforced carbon–carbon , cleavage (geology) , carbon fibers , transition metal , bond cleavage , metal , functional group , combinatorial chemistry , photochemistry , organic chemistry , double bond , composite number , materials science , polymer , geotechnical engineering , fracture (geology) , engineering , composite material
Cleavage of the carbon–carbon triple bonds of alkynes was achieved, which led to the synthesis of arylnitriles under transition‐metal‐free conditions. A vast range of terminal alkyne substrates underwent this reaction to provide the corresponding nitriles in moderate to good yields with good functional group tolerance.