An Efficient Tertiary Azidation of 1,3‐Dicarbonyl Compounds in Water Catalyzed by Tetrabutylammonium Iodide | Zendy

Dhineshkumar Jayaraman | Zendy; Prabhu Kandikere Ramaiah | Zendy

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An Efficient Tertiary Azidation of 1,3‐Dicarbonyl Compounds in Water Catalyzed by Tetrabutylammonium Iodide

Author(s) -

Dhineshkumar Jayaraman,

Prabhu Kandikere Ramaiah

Publication year - 2016

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201501374

Subject(s) - chemistry , catalysis , iodide , aqueous solution , organic chemistry , aqueous medium , iodine , green chemistry , combinatorial chemistry , reaction mechanism

An efficient azidation of 1,3‐dicarbonyl compounds led to tertiary azides in the presence of tetrabutylammonium iodide (TBAI). TBAI is used as a pre‐catalyst along with aq. tert ‐butyl hydroperoxide (TBHP) as an oxidant in aqueous medium. This operationally simple, practical, mild and green method provides an opportunity to synthesize a variety of azidated β‐keto esters, amides, and ketones in good yields.

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