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Non‐Classically Controlled Signs in a Circularly Polarised Luminescent Molecular Puppet: The Importance of the Wire Structure Connecting Binaphthyl and Two Pyrenes
Author(s) -
Nakabayashi Kazuki,
Kitamura Sayaka,
Suzuki Nozomu,
Guo Sibo,
Fujiki Michiya,
Imai Yoshitane
Publication year - 2016
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201501316
Subject(s) - luminescence , circular dichroism , chemistry , circular polarization , magnetic circular dichroism , crystallography , optics , physics , quantum mechanics , microstrip , spectral line
The circularly polarised luminescence and circular dichroism signs of the blue circularly polarised luminescence generated by two photoexcited pyrenes as puppets are controlled by the wire structure of the C 2 ‐symmetric binaphthyl as puppeteer. The experimental results, though at variance with theoretical simulation, offer a rational design in the photoexcited and ground state chiralities of luminophores.