Premium
Silver‐Catalyzed Aerobic Oxidative Decarboxylative Coupling of Arylpropiolic Acids with H ‐Phosphine Oxides: Mild and Facile Synthesis of β‐Oxophosphine Oxides
Author(s) -
Zeng YaoFu,
Tan DongHang,
Lv WenXin,
Li Qingjiang,
Wang Honggen
Publication year - 2015
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201500587
Subject(s) - chemistry , phosphine , catalysis , oxidative coupling of methane , oxidative phosphorylation , organic chemistry , combinatorial chemistry , biochemistry
A silver‐catalyzed oxidative decarboxylative coupling reaction of arylpropiolic acids with H ‐phosphine oxides by using air as the terminal oxidant was developed. The reaction proceeds smoothly under mild conditions to give β‐oxophosphine oxides in moderate to good yields. Preliminary mechanistic studies were conducted.