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Self‐Assembled Giant Vesicles Formed by Type I [3:3]‐Hexakis Adducts of C 60 Equipped with Enantiomerically Pure cyclo ‐Monomalonate Addends
Author(s) -
Ioannou Charalambos P.,
Ioannou Georgios I.,
Moushi Eleni E.,
Velonia Kelly,
Chronakis Nikos
Publication year - 2015
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201500504
Subject(s) - chemistry , enantiopure drug , adduct , vesicle , molecule , amphiphile , stereochemistry , self assembly , polymer chemistry , organic chemistry , crystallography , copolymer , enantioselective synthesis , membrane , polymer , biochemistry , catalysis
An efficient route for the synthesis of two amphiphilic type I [3:3]‐hexakis adducts of C 60 equipped with enantiopure cyclo ‐monomalonate addends was explored. Studies on their self‐assembling behavior by TEM and SEM revealed that minor modification of the size and chemical nature of their glycol‐substituted monomalonate addends and, consequently, of the shape of these giant molecules significantly influences their corresponding self‐assembling architectures.