Synthesis of a  P ‐Stereogenic PNP  t Bu,Ph  Ruthenium Pincer Complex and Its Application in Asymmetric Reduction of Ketones | Zendy

Arenas Ismael | Zendy; Boutureira Omar | Zendy; Matheu M. Isabel | Zendy; Díaz Yolanda | Zendy; Castillón Sergio | Zendy

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Synthesis of a P ‐Stereogenic PNP t Bu,Ph Ruthenium Pincer Complex and Its Application in Asymmetric Reduction of Ketones

Author(s) -

Arenas Ismael,

Boutureira Omar,

Matheu M. Isabel,

Díaz Yolanda,

Castillón Sergio

Publication year - 2015

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201500389

Subject(s) - chemistry , stereocenter , ruthenium , pincer movement , medicinal chemistry , catalysis , enantioselective synthesis , stereochemistry , asymmetric hydrogenation , combinatorial chemistry , organic chemistry

A novel P ‐stereogenic PNP t Bu,Ph ruthenium complex has been synthesized and characterized enabling the asymmetric hydrogenation of a wide range of aromatic ketones with excellent catalytic activities (up to 98 % conversion) and good levels of enantiodiscrimination (up to 95 % ee ).

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