Palladium‐Catalyzed Domino Mizoroki–Heck/Intermolecular C(sp 3 )–H Activation Sequence: An Approach to the Formation of C(sp 3 )–C(sp 3 ) Bonds | Zendy

Wang Wei | Zendy; Zhou Rong | Zendy; Jiang ZhiJie | Zendy; Wang Xin | Zendy; Fu HaiYan | Zendy; Zheng XueLi | Zendy; Chen Hua | Zendy; Li RuiXiang | Zendy

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Palladium‐Catalyzed Domino Mizoroki–Heck/Intermolecular C(sp 3 )–H Activation Sequence: An Approach to the Formation of C(sp 3 )–C(sp 3 ) Bonds

Author(s) -

Wang Wei,

Zhou Rong,

Jiang ZhiJie,

Wang Xin,

Fu HaiYan,

Zheng XueLi,

Chen Hua,

Li RuiXiang

Publication year - 2015

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201500116

Subject(s) - chemistry , palladium , heck reaction , catalysis , intermolecular force , domino , cascade reaction , medicinal chemistry , stereochemistry , organic chemistry , molecule

A palladium‐catalyzed domino Mizoroki–Heck/intermolecular unactivated C(sp 3 )–H alkylation reaction has been developed. This simple palladium nanoparticle catalytic system shows good activity and affords the dimeric dihydrobenzofuran derivatives in moderate to good yields. Furthermore, this reaction provides a new method for the elaboration of domino reactions involving a C(sp 3 )–C(sp 3 ) bond‐forming process.

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