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Controlling Helix Handedness in Water‐Soluble Quinoline Oligoamide Foldamers (Eur. J. Org. Chem. 20/2014)
Author(s) -
Dawson Simon J.,
Mészáros Ádám,
Pethő Lilla,
Colombo Cinzia,
Csékei Márton,
Kotschy András,
Huc Ivan
Publication year - 2014
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201490054
Subject(s) - chemistry , diastereomer , foldamer , helix (gastropod) , quinoline , cover (algebra) , stereochemistry , crystallography , organic chemistry , ecology , snail , biology , mechanical engineering , engineering
The cover picture shows a graphical representation of water‐soluble aromatic oligoamide foldamers frozen into ice cubes. This illustrates that P helices (blue) and M helices (red) are kinetically locked in water, allowing their separation as diastereoisomers by the incorporation of a chiral end group at the C terminus. Details are discussed in the article by A. Kotschy, I. Huc et al. on p. 4265 ff. The cover was designed by Dr. Simon Dawson, who is also the first author of the article.