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(Diacetoxyiodo)benzene‐Mediated Oxygenation of Benzylic C(sp 3 )–H Bonds with N ‐Hydroxyamides at Room Temperature
Author(s) -
Qian PengCheng,
Liu Yu,
Song RenJie,
Hu Ming,
Yang XuHeng,
Xiang JianNan,
Li JinHeng
Publication year - 2015
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201403616
Subject(s) - chemistry , benzene , oxygenation , medicinal chemistry , stereochemistry , organic chemistry , biology , ecology
A new, metal‐free method for the formation of C(sp 3 )–O bonds was established by PhI(OAc) 2 ‐mediated oxygenation of benzylic C(sp 3 )–H bonds with N ‐hydroxyamides at room temperature, in which the C(sp 3 )–H oxidation is activated by a polyflurophenylamide group.
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