Lewis‐Acid‐Catalysed Tandem Meinwald Rearrangement/Intermolecular [3+2]‐Cycloaddition of Epoxides with Donor–Acceptor Cyclopropanes: Synthesis of Functionalized Tetrahydrofurans | Zendy

Kumar Pandey Ashok | Zendy; Ghosh Asit | Zendy; Banerjee Prabal | Zendy

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Lewis‐Acid‐Catalysed Tandem Meinwald Rearrangement/Intermolecular [3+2]‐Cycloaddition of Epoxides with Donor–Acceptor Cyclopropanes: Synthesis of Functionalized Tetrahydrofurans

Author(s) -

Kumar Pandey Ashok,

Ghosh Asit,

Banerjee Prabal

Publication year - 2015

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201403590

Subject(s) - chemistry , cycloaddition , enantioselective synthesis , lewis acids and bases , tandem , intermolecular force , catalysis , aryl , acceptor , stereochemistry , medicinal chemistry , organic chemistry , molecule , materials science , alkyl , physics , composite material , condensed matter physics

A Lewis‐acid‐catalysed tandem Meinwald rearrangement/[3+2]‐cycloaddition of epoxides with donor–acceptor cyclopropanes to synthesize varieties of cis ‐2,5‐aryl‐benzyl‐substituted tetrahydrofurans is described. An enantioselective version of the same transformation was achieved using an InCl 3 –PyBOX catalyst system.

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