A Tuned Bicyclic Proazaphosphatrane for Catalytically Enhanced  N ‐Arylation Reactions with Aryl Chlorides | Zendy

Kim So Han | Zendy; Kim Min | Zendy; Verkade John G. | Zendy; Kim Youngjo | Zendy

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A Tuned Bicyclic Proazaphosphatrane for Catalytically Enhanced N ‐Arylation Reactions with Aryl Chlorides

Author(s) -

Kim So Han,

Kim Min,

Verkade John G.,

Kim Youngjo

Publication year - 2015

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201403428

Subject(s) - chemistry , bicyclic molecule , aryl , ligand (biochemistry) , catalysis , medicinal chemistry , combinatorial chemistry , stereochemistry , organic chemistry , biochemistry , alkyl , receptor

The N ‐arylation of various amines with aryl chlorides proceeded in good‐to‐excellent yields in the presence of P[N{( p ‐NMe 2 )C 6 H 4 CH 2 }CH 2 CH 2 ] 3 N ( 1e , a new electron‐rich proazaphosphatrane ligand) and small amounts of Pd 2 (dba) 3 (dba = dibenzylideneacetone). This catalytic system was also very effective for the synthesis of carbazoles.

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