Ceric Ammonium Nitrate (CAN) Promoted Pd II ‐Catalyzed Substrate‐Directed  o ‐Benzoxylation and Decarboxylative  o ‐Aroylation | Zendy

Santra Sourav Kumar | Zendy; Banerjee Arghya | Zendy; Khatun Nilufa | Zendy; Patel Bhisma K. | Zendy

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Ceric Ammonium Nitrate (CAN) Promoted Pd II ‐Catalyzed Substrate‐Directed o ‐Benzoxylation and Decarboxylative o ‐Aroylation

Author(s) -

Santra Sourav Kumar,

Banerjee Arghya,

Khatun Nilufa,

Patel Bhisma K.

Publication year - 2015

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201403367

Subject(s) - ceric ammonium nitrate , chemistry , catalysis , substrate (aquarium) , decarboxylation , nitrate , medicinal chemistry , ammonium , organic chemistry , oceanography , grafting , geology , polymer

Inexpensive ceric ammonium nitrate (CAN) is an efficient oxidant for the Pd‐catalyzed substrate‐directed o ‐benzoxylation and decarboxylative o ‐aroylation processes. In the presence of CAN, the reaction of directing arenes with carboxylic acids resulted in o ‐benzoxylated products, whereas a decarboxylative o ‐aroylation occurred by using α‐keto acids, which led to the formation of o ‐aroylation products.

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