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Ceric Ammonium Nitrate (CAN) Promoted Pd II ‐Catalyzed Substrate‐Directed o ‐Benzoxylation and Decarboxylative o ‐Aroylation
Author(s) -
Santra Sourav Kumar,
Banerjee Arghya,
Khatun Nilufa,
Patel Bhisma K.
Publication year - 2015
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201403367
Subject(s) - ceric ammonium nitrate , chemistry , catalysis , substrate (aquarium) , decarboxylation , nitrate , medicinal chemistry , ammonium , organic chemistry , oceanography , grafting , geology , polymer
Inexpensive ceric ammonium nitrate (CAN) is an efficient oxidant for the Pd‐catalyzed substrate‐directed o ‐benzoxylation and decarboxylative o ‐aroylation processes. In the presence of CAN, the reaction of directing arenes with carboxylic acids resulted in o ‐benzoxylated products, whereas a decarboxylative o ‐aroylation occurred by using α‐keto acids, which led to the formation of o ‐aroylation products.