Synthesis of Isoindoles by One‐Electron Reductions of Dibenzo[1,4]diazocines | Zendy

Bovenkerk Marcel | Zendy; Esser Birgit | Zendy

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Synthesis of Isoindoles by One‐Electron Reductions of Dibenzo[1,4]diazocines

Author(s) -

Bovenkerk Marcel,

Esser Birgit

Publication year - 2015

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201403315

Subject(s) - isoindole , chemistry , quantum chemical , computational chemistry , electron , photochemistry , combinatorial chemistry , chemical synthesis , stereochemistry , organic chemistry , molecule , biochemistry , in vitro , physics , quantum mechanics

A synthetic protocol to isoindoles is reported through one‐electron reductions of dibenzo[1,4]diazocines. The utility of the approach has been demonstrated through the synthesis of six novel isoindole derivatives. Photophysical measurements revealed emissions between 440 and 460 nm. A reaction mechanism, supported by experimental results and quantum chemical calculations, is postulated.

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